It's normal and quite common for new climbing shoes to hurt a little bit. With that said, they should not cause throbbing pain that lasts after you take them off.
Depending on the type of shoes and their material, new climbing shoes usually have a break in period, which can take a few climbing sessions to get through. During this break in period, your shoes will start to change in shape and fit, molding themselves to your feet. This process can be very uncomfortable and a little bit painful, depending on the size you bought.
Keep in mind that this break in period varies depending on the type of climbing shoe, the material it is made of, and the size of the shoe. Synthetic shoes may stretch at the most half a size, while leather shoes can stretch up to 2 whole sizes.
If your shoes are synthetic, and they are causing you pain, keep in mind that they may not actually have a very noticeable break in period, which means they may just not be right for you. You may also not be used to wearing climbing shoes that are tight, which also takes time to get used to.
Yes, you can go bouldering alone in a climbing gym. Bouldering in climbing gym doesn't require any special safety equipment as the gyms have everything that is needed.
Bouldering outdoors, on the other hand, would require at least one more person for safety reasons. The person would be your spotter, and would be there to help in case anything goes wrong.
Because leaving them on in between routes can end up being painful, shortening your climbing session, and making every attempt on the route more and more painful and less efficient.
Taking your shoes off in between routes lets your feet rest a little bit.
Take care of them and take care of your feet.
Make sure you let your shoes dry after climbing sessions, and don't put them in your bag. Also make sure your feet are clean before putting them on.
Yes, leather climbing shoes stretch and can even become quite baggy if you choose the wrong size and they stretch a lot. Synthetic shoes barely stretch, and even if they do, its so minimal that most don't even notice a difference.
Loose shoes are great for warm-up routes, but generally bad for hard routes. Tight shoes are great for hard routes, and can be used for warm-up routes, but if you have looser ones, you may prefer them for the warm-ups over the tight shoes.
A chalk bag is not required, neither is chalk itself, but it is very helpful, especially if the holds are a little bit "over-touched", and if you sweat from your palms.
Pulley and skin damage are probably the most common finger injuries or finger damage for climbers.
They can both normally be prevented, though, if the climber is first of all aware of these two risks and knows how to minimize them, which largely means paying attention and listening to your body.